Electrochemical Activation of Catalysis

Electrochemical Activation of Catalysis

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This book describes the phenomenology, theory and potential applications of the phenomenon of electrochemical promotion, where electrochemically induced ion spillover activates and controls heterogeneous catalysis. The origin of electrochemical promotion is discussed in light of a plethora of surface spectroscopic and electrochemical techniques. Electrochemical and classical promotion are compared, their common rules are identified and promotional kinetics are rigorously modeled and compared with experiment.Chem. 89(1), 570-576 (1988). M.T.M. Koper, and R.A.van Santen, Electric field effects on CO and NO adsorption at the ... Chem. 96(21), 8509-8516 (1992). E. Gileadi, Electrode kinetics: for chemists, chemical engineers, and materials ... G.A. Somorjai, Chemistry in Two Dimensions: Surfaces, Cornell University Press (1981). ... I. Metcalfe, Electrochemical Promotion of Catalysis II: The role of stable spillover species and prediction of reaction rate modification, J. Catal. ... 332 CHAPTER 6.

Title:Electrochemical Activation of Catalysis
Author: Costas G. Vayenas
Publisher:Springer Science & Business Media - 2001

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